employee_emails = ["bdoe@email.com", "mmarkson@email.com"]

employee_details = [
    {
        "first_name": "Bob", 
        "last_name": "Doe", 
        "address": {
            "city": "New York", 
            "street": "1st Street", 
            "house_number": 1
        }
    },
    {
        "first_name": "Mark", 
        "last_name": "Markson", 
        "address": {
            "city": "San Diego", 
            "street": "2nd Street", 
            "house_number": 2
        }
    }
]

employees = dict(zip(employee_emails, employee_details))
pp.pprint(employees)